Absolute
              Time Scales: Early Strategies
              
          Relative dating provided a history of life on Earth, a history
                that clearly showed changes in geology, climate, and life. Today
                radiometric dating places absolute dates on the relative time
                scale. There were many early attempts at establishing an absolute
                time scale before the use of radiometric dating. Some of these
                efforts were biblically based while others represented non-religious
                estimates. We will survey the work of specific individuals to
                explore a variety of strategies.
              Biblical Chronology
              James Ussher (1581-1656) Archbishop of Armagh (Ireland) developed
                  a chronology, entitled Annalium pars postierior in 1654, based
                  upon the life spans of people in the Bible and other ancient
                  documents. Ussher calculated the date of creation to have been
                  nightfall preceding October 23, 4004 BC. The 9:00 a.m. time
                  of creation often attributed to Ussher was actually from previous
                  work by John Lightfoot (1602-1675) a distinguished biblical
                  and Greek scholar (Dalrymple, 1991, p. 21).
              Decline in Sea Level
  Benoit de Maillet (1656-1738) was a French anthropologist and
                  diplomat. de Maillet estimated the Earth was 2 billion years
                  old. de Maillet's estimate was based upon declining sea levels.
                  Fossils of ocean organisms on land and in the mountains seemed
                  to support that the Earth was once covered by one large ocean.
                  As this ocean evaporated, water levels declined. de Maillet
                  used measured sea level changes to estimate when the Earth
                  was completely covered with water. This theory was based on
                  Descartes theory on the birth and death of the sun and planets.
                  de Maillet's estimate was presented in a fictional conversation
                  between a French missionary and an Indian philosopher Telliamed
                  (de Maillet spelled backwards). de Maillet never published
                  his work for fear of repercussions. Telliamed was published
                  by Abbé J.B. le Mascrier in 1748. le Mascrier did not
                  publish under his real name and changed the estimate from millions
                  to billions. Telliamed was not published in its original format
                  until 1968. Although de Maillet’s formulations were made
                  without knowledge of geological uplift they were important
                  because they represented logical extrapolations from measurements
                  taken from nature. Furthermore, de Maillet’s method excluded
                  human life spans as a measurement (Dalrymple 1991, p.27). The
                  dynamic nature of Earth’s surface was unknown to Maillet,
                  but even during his time it was known that sea levels had dropped
                  in some areas and were rising in others. Sea level change was
                  quickly abandoned as an Earth dating method.
              Cooling of Earth
  Georges-Louis Lecterc, Comte de Buffon (1707-1788) was a French
                  naturalist. Buffon calculated the world to be much older than
                  Ussher. In his 1778 publication Epochs of Nature Buffon calculated
                  the age of the Earth to be 75,000 years. Buffon arrived at
                  this age by heating small iron spheres and scaling their cooling
                  rates to an earth-sized mass. Sir Isaac Newton was the first
                  to suggest using this strategy to estimate the cooling rate
                  of Earth. The Catholic Church in France condemned Buffon for
                  his calculation and burned his books. Lord Kelvin would later
                  greatly increase the precision of Buffon’s crude methods
                  (Burchfield 1990, p. 34). Kelvin’s methods were mathematically
                  elegant and deductively sound; however, without the knowledge
                  of energy created from radioactive decay his premises and thus
                  his conclusions were wrong. Cooling of the Earth has been abandoned
                  as a method to determine Earth’s age.
              Cooling of Sun
  Hermann Ludwig Ferdinand von Helmholtz (1821-1894) was a German
                  physician and physicist. Helmholtz used the cooling of the
                  sun to estimate Earth's age. In 1856 Helmoltz calculated that
                  it would take the Sun 22 million years to condense down to
                  its current diameter and temperature from a nebula of dust
                  and gas. He assumed the heat of the sun was generated from
                  gravitational contraction. Lord Kelvin’s version of the
                  Helmholtz model included heat generated by meteoric impacts.
                  The gravitational potential energy of the meteor would be converted
                  to kinetic energy and upon collision into heat energy. Although
                  meteoric impact was not supported by the observations made
                  by astronomers Kelvin could see no alternative to gravitational
                  potential energy (Bachall, 2000). Kelvin’s calculations
                  indicated that even the most vigorous chemical reactions could
                  not account for the known age of human civilization, thus chemical
                  reactions could not be a heat source for the sun. With the
                  discovery of nuclear reactions the model developed by Helmholtz
                  and Kelvin became obsolete.
              Weathering & Erosion
  Charles Darwin speculated on the weathering and erosion of the
                  Weald Chalk formations in his book The Origin of Species by
                  Means of Natural Selection. Chalk formations in North and South
                  Downs at one time extended over the sandstone and clay layers
                  of the High and Low Weald forming a dome. This chalk layer
                  was eroded and now only exits at the edges. Darwin sets up
                  his scientific intuition from his personal geologic field observations.
                  Darwin asks the reader to imagine the immense time needed to
                  weather, erode, and deposit rock. Darwin turns attention to
                  the chalk formations of the Weald and, with what he argues
                  are reasonable rates of weathering and erosion, concludes the
                  denudation of the Weald required 300,000,000 million years
                  (Darwin 1859/2004, pp. 230-232). Although not an estimate for
                  the age of Earth, Darwin’s reasoning represents an interesting
                  attempt at using denudation (exposing of rock strata through
                  erosion) to date a rock formation. Kelvin was critical of Darwin’s
                  estimate when writing on the age of the Sun though cooling.
                  Kelvin believed that the Sun could not have existed for the
                  time required by Darwin’s theory; he was working without
                  knowledge of nuclear energy. Darwin was so shaken by Kelvin’s
                  criticism that he removed his estimate in later editions of
                  the Origin of Species (Bachall 2000). Kelvin’s impressive
                  mathematical models based on physics also influenced the science
                  of geology in both positive and negative ways. The limits Kelvin’s
                  quantitative methods placed on Earth’s age had the unfortunate
                  effect of making uniformatarianism less tenable. Due to Kelvin’s
                  work the science of geology became more quantitative and geologists
                  and physicists interacted with each other (Burchfield 1990,
                  pp. 10-12). It was clear to both sides that scientific hypotheses
                  and theories must be internally coherent and externally consistent
                  with findings in other fields of science. 
              Sediment Accumulation
  John Phillips (1800-1874) was an English geologist. Phillips
                  came under the charge of his uncle William Smith (the father
                  of modern geology) when his parents died. In 1860 Phillips
                  utilized sediment accumulation to estimate the Earth's age
                  at 38 to 96 million years. As a method of determining the age
                  of the Earth, sediment accumulation involved comparing measured
                  rates of continental erosion with the aggregate thickness of
                  sedimentary rock layers from successive time divisions. Charles
                  D. Walcott (1850-1927) an American geologist and paleontologist
                  is probably best known for his discovery and subsequent work
                  on fossils of the Burgess Shale formation of British Columbia,
                  Canada. Walcott made the most detailed model of sediment accumulation
                  (Dalrymple 1991, pp. 59-66). Walcott’s estimate was between
                  35 and 80 million years. Many uncertainties plagued this method
                  of age determination. These uncertainties included the relationship
                  between areas of erosion and areas of deposition, the rates
                  of sedimentation, and the missing time represented by unconformities,
                  etc. (Burchfield 1990, pp. 16-18). Furthermore, this method
                  could only attempt to reach back to the Cambrium period. These
                  rock layers did not reveal the majority of Earth’s history
                  (Dalrymple 1991, pp 68-69). Sediment accumulation was eventually
                  abandoned as a method to determine the age of the Earth.
              Tidal Effects
  William Thompson, Lord Kelvin (1824-1907) was an Irish mathematician,
                  physicist and engineer. Between the years of 1862 and 1897
                  Kelvin used multiple methods to calculate the age of the Earth.
                  These methods included cooling of the Earth, Sun, and Earth
                  tidal effects. Immanuael Kant (1724-1804) a German philosopher
                  was the first to recognize the breaking effect of the tides
                  on Earth’s rotation. Kelvin was the first to Estimating
                  Earth's age using tidal effects (Dalrymple, 1991, p. 48). As
                  the tides rise and fall gravitational friction causes a reduction
                  in
                  the Earth’s
                  rotation, Moons orbital velocity and an increase in the Moon’s
                  distance from Earth. Kelvin was the first to show that a transfer
                  of angular momentum from the Earth to the Moon caused the Moon
                  to recede from the Earth. Kelvin's estimates using these different
                  methods ranged from 10 million to less than 1 billion years.
                  The 1 billion year figure was arrived at using tidal effects.
                  George H. Darwin (1845-1912) a mathematical astronomer was
                  the son of Charles Darwin. G.H. Darwin refined the method of
                  determining Earth’s age using tidal effects to a high
                  degree (Dalrymple 1991, pp 47-52). Darwin’s minimum age
                  for the Earth using this method was 56 million years. Darwin
                  believed the Earth was most likely much older. Using the Moon’s
                  recession rate from the Earth due to tidal effects did not
                  become an accurate method for determining Earth’s age
                  until the movement of the continents described by Plate Tectonic
                  theory became part of the mathematical model during the 1960’s.
                  The current model is supported by paleontological evidence
                  in the form of tidal rhythmites or tidally laminated sediments
                  (Thompson, 1999). The current age of the Earth using this model
                  is in agreement with radiometric dating.
              Salt Accumulation in Oceans
  Edmund Halley (1656-1742) was an English Astronomer. In 1715
                  Halley hypothesized that the age of the Earth could be calculated
                  by determining the rate at which salt is added to the ocean
                  through erosion. Halley recommended that salt concentrations
                  be measured on a regular basis to establish the rate at which
                  they were added so that future scientists could use his method.
                  Thomas Mellard Reade (1832-1909) an English geologist was the
                  first to apply Halley’s suggestion of using the oceans
                  as a sort of “salt clock” in 1876. Instead of using
                  changes in salt concentrations over time as suggested by Halley,
                  Reade used estimates for the amount of salts added by erosion.
                  Reade knew the estimated amounts of chloride and sulfate salts
                  added to the oceans from the major rivers of the world. He
                  used this data to determine how long it would take the ocean
                  to reach its present salt concentrations. His estimate was
                  25 million years for sulfates and 200 million years for chlorides
                  (Dalyrumple 1991, p. 53). Reade called his salt clock model “chemical
                  denundation”. John Joly (1857-1933) an English geologist
                  would refine Reade’s model. Jolly used sodium concentrations
                  as his salt clock because he believed that sodium is added,
                  but not withdrawn from the oceans. Jolly’s estimate for
                  Earth’s age was 90 to 100 million years. Today we know
                  that the salts are not only added but also removed from the
                  ocean. Salt accumulation in the oceans was abandoned as a way
                  to determine Earth’s age.
              Eccentricity
                    of Mercury’s
                  Orbit
              In 1918 Harold Jeffreys (1891-1989), British Astronomer and Geophysicist,
              used the changing eccentricity of Mercury's orbit 
              over time to estimate the age of our solar system to be 3 billion
              years (Dalrymple, 1991, p. 17). All of the above methods would
              become obsolete with the discovery of radioactivity.
              Bibliography:
              Bachcall, J.N. (2000). How the Sun Shines. Published on Nobelprize.org.
                see http://nobelprize.org/nobel_prizes/physics/articles/fusion/index.html
              Burchfield, J.D. (1990). Lord Kelvin and the Age of the Earth.
                Chicago: The University of Chicago Press.
              Dalrymple, G. B. (1991). The Age of the Earth. Stanford California:
                Stanford University Press.
              Darwin, C. (2004). The Origin of Species. New York: Fine Creative
                Media. (Originally published in 1859).
              Geology of the Weald printed on Highweald.org see: http://www.highweald.org/text.asp?PageId=256
              Thompson, T. (1999). The Recession of the Moon and the Age of
                the Earth-Moon System. The TalkOrigin Archieves see: http://www.talkorigins.org/faqs/moonrec.html
                
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